Original paper

The crystal structure of paranatrolite

Seryotkin, Yurii V.; Bakakin, Vladimir V.; Belitsky, Igor A.

Abstract

Paranatrolite from the Khibiny massif, Kola Peninsula, Russia, Na1.88K0.22Ca0.06[Al2.24Si2.76O10]·3.1H2O, is monoclinic (space group Cc, Z = 4). For better comparison of this mineral with the related structure of natrolite , we have selected a pseudo-orthorhombic setting in F1d1 (a = 18.971(4), b = 19.204(3), c = 6.5952(12) Å, β = 91.601(18)°, Z = 8). The dominant Na+ cations are situated near the sodium positions in the natrolite structure. Additional positions occupied by K+ are located in the eightmembered rings. H2O molecules are located in four independent positions, two being occupied statistically. The Na-polyhedra correspond to distorted NaO3(H2O)3 octahedra forming chains along the c axis by sharing common H2O–H2O edges and H2O vertices. The availability of potassium in the structure results in two configurations for the coordination environment of Na + .

Keywords

zeolitenatroliteparanatrolitetetranatrolitecrystal structure