Anthropogenic origin of salt crusts on sandstone sculptures of Prague's Charles Bridge (Czech Republic): Evidence of mineralogy and stable isotope geochemistry
Přikryl, Richard; Svobodová, Jiřna; Zák, Karel; Hradil, David
European Journal of Mineralogy Volume 16 Number 4 (2004), p. 609 - 617
published: Jul 15, 2004
ArtNo. ESP147051604005, Price: 29.00 €
A prestigious Czech national monument the medieval Charles Bridge in the historic city centre of Prague is enclosed with sculptures carved from local sandstones. The stone exhibits varying weathering phenomena that are manifested mostly by surface blackening and local exocrust formation. Influences of the original stone composition and of atmospheric pollution on the formation of exocrust were evaluated using detailed mineralogical study and geochemistry of stable isotopes. The s tudied exocrusts are gypsum-dominated. Sulphur and oxygen isotope data (δ34S sulphate values range from +3.3 to +7.5 ‰ CDT with average +4.8 ‰ CDT from 15 measurements; δ18O values range from +6.4 to +9.7 ‰ SMOW with average +8.3 ‰ SMOW from 8 measurements), on sulphate, and absence of suitable sulphur source in the stone itself, strongly support anthropogenic atmospheric source of sulphur. Presence of other minor sulphates (of zinc, a mmonium, magnesium, and potassium) can be explained by complex restoration and conservation treatments of the sculptures in the past. The sculptural stone quartz sandstone derived from Cretaceous sedimentary cover of the Bohemian Massif is deficient in both calcium and other elements forming the sulphate crusts. The results of this study show that some chemicals used for the restoration of the stone sculptures can exacerbate stone weathering especially when applied in heavily p olluted urban areas.