On multi-phase mineral inclusions associated with microdiamond formation in mantle-derived peridotite lens at Bardane on Fjortoft, west Norway
Carswell, Dennis A.; van Roermund, Herman L.M.
published: Mar 3, 2005
ArtNo. ESP147051701004, Price: 29.00 €
This paper reports a study of the microstructures and mineral inclusions associated with microdiamond-formation in samples of a garnet websterite pod exposed within a mantle-derived peridotite body at Bardane on Fjørtoft, western Norway. This pod is interpreted to have originally comprised a megacrystic assemblage of orthopyroxene + clinopyroxene + garnet + Cr-spinel (Cr* ≈ 75) + minor olivine that probably crystallised within a mid-Proterozoic (1651±47 Ma) mantle diapir/plume at conditions of around 1410°C and 3.2 GPa. The observed microdiamonds are clearly not part of this early (M1) paragenesis but formed later, following a deformation-induced fluid infiltration event.The diamond and other carbon-phase mineral inclusions rarely occur in isolation, instead in composite aggregates with other, mostly micro-scale, mineral inclusions that include phlogopite, kalsilite, Cr-spinel (Cr* ≈ 55), magnesite, Ba-Mg carbonate, Fe-Ni sulphide, Cl-apatite, rutile, zircon and monazite. Thus a metasomatic fluid has clearly introduced other elements (such as K, Ba, Ti, Fe, S, P, Cl, Zr, Cl, Th, and Nb) into this peridotite body, in addition to carbon.Back-scattered electron SEM images demonstrate that the introduced suite of mineral inclusions is spatially intimately associated with M2 generation grains of orthopyroxene, clinopyroxene, garnet and Cr-spinel (Cr* ≈ 55) that occur both as internally-exsolved phases within deformed and highly-strained M1 megacrysts and as a coronitic boundary network of grains precipitated between physically-fragmented M1 megacrysts.To date the microdiamonds have been found to be only rarely preserved as a component of multi-phase mineral inclusions that are doubly armoured in M2 Cr-spinel (Cr* ≈ 55) in turn enclosed within M2 generation garnet. Most carbon phase inclusions are now composed of disordered graphite thought most likely to have replaced pre-existing diamond.The M2 mineral assemblage, with which the introduced microdiamond-bearing mineral inclusion suite is intimately associated, is considered to have formed during the Palaeozoic Caledonian orogeny on the basis of a Sm-Nd errorchron age of 518±78 Ma for the internally exsolved M2 mineral assemblage at Bardane. This determined age is most likely a mixed age between the apparent age of the M1 assemblage and the time of M2 deformation-triggered exsolution and fluid infiltration. Thus microdiamond formation is interpreted to have probably occurred during the Scandian phase of the Caledonian orogenic cycle when this fragment of lithospheric mantle was introduced into a slab of Baltica margin continental crust that experienced short-lived deep-level subduction and attendant ultra-high pressure eclogite-facies metamorphism. The supercritical fluid responsible for the introduction of carbon and other elements into this peridotite body most likely originated from prograde dehydration and decarbonation reactions within the enclosing slab of continental crust gneisses. The microdiamond formation is considered to have occurred at the P-T conditions of ca. 875±25°C and 4.1±0.2 GPa estimated for the formation of the M2 mineral assemblage within the Bardane peridotite body.