Original paper

On the transformation pathways of alpha-PbO2-type TiO2 at the twin boundary of rutile bicrystals and the origin of rutile bicrystals

Shen, Pouyan; Hwang, Shyh-Lung; Chu, Hao-Tsu; Yui, Tzen-Fu; Pan, Chiennan; Huang, Wuu-Liang


Extraction and electron irradiation (under transmission electron microscopy) of an epitaxial nanometer-thick α-PbO2-type TiO2 slab between twinned rutile bicrystals in ultra-high pressure metamorphic rock caused phase changes into a modified fluoritetype and then an amorphous phase. This martensitic-type transition process accounts for the dislocations and stacking faults of the slab and disordering of Ti in the adjoined rutile bicrystals. Additional hydrothermal experiments of sol-gel TiO2-Al2O3 performed at 8.5–9 kbar and 675–800°C in the piston-cylinder apparatus indicated that twinned rutile bicrystals were shaped in mirror image without the formation of α-PbO2-type TiO2 slab at the twin boundary and with no other planar defects for the bicrystals. The twinned bicrystals can be rationalized by growth and/or coalescence processes. Accordingly, it is not justified to assume a precursor phase of α-PbO2-type structure for twinned rutile bicrystals when there is no such relic. Rutile, unless exsolved epitaxially from a host mineral such as garnet, does not constitute evidence for unusually deep burial for ultra-high pressure terranes.


alpha-pbo2-type tio2transformation pathtwinned rutileultra-high pressuremetamorphism