Original paper

Retentivity of CO2 in fluid inclusions in mantle minerals

Yamamoto, Junji; Otsuka, Kazuhiko; Ohfuji, Hiroaki; Ishibashi, Hidemi; Hirano, Naoto; Kagi, Hiroyuki


To assess the capacity of fluid inclusions in mantle minerals for CO2 retention, annealing experiments were conducted for two mantle xenoliths with CO2 inclusions for 8 days at 1000°C under atmospheric pressure and f O2 of 1011 MPa. The results show no marked decrease in the CO2 density of the CO2 inclusions for any examined minerals - olivine, orthopyroxene, clinopyroxene, or spinel. The CO2 density of CO2 inclusions in olivine in the present mantle xenoliths is lower than that in pyroxenes or spinel. Results of previous studies indicate that the low CO2 density in olivine is attributable to plastic deformation of olivine around CO2 inclusions during annealing in ascending magma. Results of this study present fundamental implications for deformation mechanisms that arise from internal pressure of fluid inclusions in silicate minerals. We calculated the stress field in minerals having a CO2 inclusion. Results show a steep stress gradient in the host around the inclusion. Such local stress in the mineral induces a local rise in the density of dislocations around the CO2 inclusions. The orthopyroxene used for this study showed a sparse distribution of dislocations around a CO2 inclusion, whereas olivine showed dense dislocations around CO2 inclusions, implying that the low CO2 density of the CO2 inclusions in olivine results from volume expansion of the CO2 inclusions through plastic deformation of the host mineral during annealing of the xenoliths in ascending magma. In this respect, constancy of CO2 density during the annealing experiments for all minerals is an interesting finding. Regarding olivines, the reduction of internal pressure of the CO2 inclusions or interaction of the dense dislocations possibly inhibits decrepitation or further volume expansion of the CO2 inclusions during annealing experiments. However, pyroxenes and spinel show higher and similar CO2 density, which reflects the resistance to plastic deformation and which indicates the effectiveness of CO2 inclusions in these minerals as a depth probe for mantle xenoliths.


micro-raman spectroscopyfluid inclusionco2mantle xenolithplastic deformationgeobarometry