Original paper

Fe3O4 activities in Fe-Ti spinel solid solutions

Woodland, Alan B.; Wood, Bernard J.

European Journal of Mineralogy Volume 6 Number 1 (1994), p. 23 - 38

52 references

published: Feb 4, 1994
manuscript accepted: Sep 29, 1993
manuscript received: Jan 21, 1993

DOI: 10.1127/ejm/6/1/0023

BibTeX file

ArtNo. ESP147050601004, Price: 29.00 €

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Abstract

Abstract The activity of Fe3O4 in Fe3O4-Fe2TiO4 solid solutions has been experimentally determined at 800 oC and 900 oC at 1 atm pressure. The activity-composition relations deviate markedly from "ideal" (a = X2) behavior, requiring consideration of Fe2+-Fe3+ order on the ulvöspinel-magnetite join. We have developed a solution model that takes explicit account of order-disorder and the measured activity-composition relations. The derived interaction parameters fit our activity-composition data together with other activity and cation distribution data available in the literature over the temperature range of 800-13002C

Keywords

titaniferous magnetiteelectrochemical measurementsactivity-composition relationsthermodynamicscation ordering