Original paper

Coarse-grained siderite in canga, Quadrilátero Ferrífero of Minas Gerais, Brazil: mineralogical evidence for the longevity of ferruginous duricrust

Cabral, Alexandre Raphael; Zapparoli, Adriana; Motta, Eduardo Geraldo Melo; Kwitko-Ribeiro, Rogerio

Abstract

The canga at Capitão do Mato, an iron-ore deposit in the Quadrilátero Ferrífero of Minas Gerais, Brazil, contains cavities filled with coarse-grained crystals of siderite, commonly exceeding 1 mm across. The siderite has δ13C values between -16.7 and -11.5 ‰. The siderite-bearing canga shows enrichments in some trace metals, particularly in mercury. These observations suggest that the siderite formed from solutions rich in dissolved organic matter derived from overlying organic material that accumulated in peat bogs or lakes. The former are known to have developed over the canga during the Tertiary, and they could rapidly have been removed by intense denudation as a result of neotectonic activity. However, the longevity of canga in relation to erosion likely allowed the extremely slow precipitation rates of siderite to form coarse-grained crystals.

Keywords

sideritecangaδ13cquadrilÁtero ferrÍferominas geraisbrazil